Dual Studies of Photo Degradation and Adsorptions of Congo Red in Wastewater on Graphene-Copper Oxide Heterostructures.

This work comprehensively studies both the photocatalytic degradation and the adsorption process of Congo red dye on the surface of a mixed-phase copper oxide-graphene heterostructure nanocomposite. Laser-induced pristine graphene and graphene doped with different CuO concentrations were used to study these effects. Raman spectra showed a shift in the D and G bands of the graphene due to incorporating copper phases into the laser-induced graphene. The XRD confirmed that the laser beam was able to reduce the CuO phase to Cu2O and Cu phases, which were embedded into the graphene. The results elucidate incorporating Cu2O molecules and atoms into the graphene lattice. The production of disordered graphene and the mixed phases of oxides and graphene were validated by the Raman spectra. It is noted from the spectra that the D site changed significantly after the addition of doping, which indicates the incorporation of Cu2O in the graphene. The impact of the graphene content was examined with 0.5, 1.0, and 2.0 mL of CuO. The findings of the photocatalysis and adsorption studies showed an improvement in the heterojunction of copper oxide and graphene, but a significant improvement was noticed with the addition of graphene with CuO. The outcomes demonstrated the compound's potential for photocatalytic use in the degradation of Congo red.

Adsorption Study of Congo Red Dye from Synthetic Wastewater at Different Concentrations Using Zinc Sulfide Nanoparticles.

Zinc sulfide (ZnS) nanoparticles were fabricated using the chemical precipitation method. The X-ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM) techniques were used to investigate the structural parameters of the formed ZnS. The hexagonal crystal structure of the Zn and ZnS phases was formed. The average crystallite size of the ZnS phase is 10.3 nm, which is much smaller than that of the Zn phase (54.5 nm). Several frequencies and phonon modes were detected in the Raman scattering spectrum belonging to the ZnS nanoparticles. The synthesized ZnS nanoparticles were used as catalysts to eliminate the Congo red (CR) dye, with different concentrations, from synthetic wastewater. The impact of the CR dye concentration and shaking period on the adsorption of CR was thoroughly investigated, and various adsorption kinetic models were tested. After 3 h of shaking, the adsorption efficiency reached 26.01% for 40 mg/L CR dye and 27.84% for 20 mg/L CR dye. The adsorption capacities of the CR dye in the presence of ZnS are 16% and 9% for 40 and 20 mg/L, respectively. Based on the correlation factor, the intraparticle diffusion kinetic model was considered the best of the tested models.

Evaluation of endothelial cell adhesion onto different protein/gold electrodes by EIS.

To study cell attachment to biomaterials, several proteins such as fibronectin, collagen IV, heparin, immunoglobulin G, and albumin have been deposited onto polystyrene adsorbed on a self-assembled monolayer (silane or thiol) on glass or gold, respectively. The different steps of this multilayer assembly have been characterized by electrochemical impedance spectroscopy (EIS). These data are compared to those of adhesion rate, viability percentage, and cytoskeleton labeling for a better understanding of the cell adhesion process to each protein. All the proteins are endothelial cell adhering biomolecules but not with the same features. A linear relationship has been established between adhesion rate and resistance of the endothelial cell/protein interface for all negatively charged proteins.

Electrical probing of endothelial cell behaviour on a fibronectin/polystyrene/thiol/gold electrode by Faradaic electrochemical impedance spectroscopy (EIS).

The electrochemical impedance spectroscopy (EIS) technique has been shown to be an effective tool for monitoring endothelial cell behaviour on a multilayer functionalised gold electrode. Polystyrene, a reproducible model substrate, is deposited as a thin layer on a thiol functionalised gold electrode. Fibronectin, a protein promoting endothelial cell adhesion, is then adsorbed on the polystyrene surface. The different steps of this multilayer assembly are characterized by Faradaic impedance. The charge transfer resistance and the capacitance for the total layer are modified at each step according to the electrical properties of each layer. This gives the endothelial cells' electrical state in terms of its resistive and capacitive properties. In this study, the endothelial cell layer presents a specific charge transfer resistance equal to 1.55 kOmega cm(2) with no large defects in the cell layer, and a specific capacitance equal to few microF cm(-2) explained by the existence of pseudopods. These electrical properties are correlated to the endothelial cell viability, adhesion and cytoskeleton organization.